Laboratoire de Reconnaissance Ionique et Chimie de Coordination, Service de Chimie Inorganique et Biologique, UMR E-3 CEA/UJF, FRE3200 CNRS, CEA-Grenoble, INAC, 17 rue des Martyrs, 38054 Grenoble cedex 9, France.
J Am Chem Soc. 2010 Dec 15;132(49):17374-7. doi: 10.1021/ja1089364. Epub 2010 Nov 19.
The reaction of U(III) with Schiff base ligands and the reduction of U(IV) Schiff base complexes both promote C-C bond formation to afford dinuclear or mononuclear U(IV) amido complexes, which can release up to four electrons to substrates through the oxidative cleavage of the C-C bond.
U(III)与希夫碱配体的反应以及 U(IV)希夫碱配合物的还原均促进 C-C 键形成，得到双核或单核 U(IV)酰胺配合物，这些配合物可以通过 C-C 键的氧化断裂向底物释放多达四个电子。
