G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950 Nizhny Novgorod, Russia.
Molecules. 2022 Jun 19;27(12):3928. doi: 10.3390/molecules27123928.
A combination of different types of redox-active systems in one molecule makes it possible to create coordination compounds with extended redox abilities, combining molecular and electronic structures determined by the features of intra- and intermolecular interactions between such redox-active centres. This review summarizes and analyses information from the literature, published mainly from 2000 to the present, on the methods of preparation, the molecular and electronic structure of mixed-ligand coordination compounds based on redox-active ligands of the o-benzoquinone type and ferrocenes, ferrocene-containing ligands, the features of their redox properties, and some chemical behaviour.
一种分子中结合不同类型的氧化还原活性体系，使得有可能创造具有扩展氧化还原能力的配位化合物，将分子和电子结构结合起来，由这种氧化还原活性中心之间的分子内和分子间相互作用的特征决定。这篇综述总结和分析了文献中的信息，这些信息主要发表于 2000 年至今，内容涉及基于邻苯醌型和二茂铁型氧化还原活性配体、二茂铁配体的混合配体配位化合物的制备方法、分子和电子结构、氧化还原性质的特点以及一些化学行为。
