P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, 19104, USA.
Chem Commun (Camb). 2012 May 21;48(41):4977-9. doi: 10.1039/c2cc31601c. Epub 2012 Apr 11.
Pentavalent uranium complexes of the formula U(V)X(2)N(SiMe(3))(2) (X = F(-), Cl(-), Br(-), N(3)(-), NCS(-)) are accessible from the oxidation of U(III)N(SiMe(3))(2) through two sequential, one-electron oxidation reactions (halides) and substitution through salt metathesis (pseudohalides). Uranium(v) mixed-halides are also synthesized by successive one-electron oxidation reactions.
五价铀配合物的公式 U(V)X(2)N(SiMe(3))(2)（X = F(-)，Cl(-)，Br(-)，N(3)(-)，NCS(-)）可从 U(III)N(SiMe(3))(2)的氧化通过两个连续的单电子氧化反应（卤化物）和通过盐的复分解反应（拟卤化物）来取代。铀（v）混合卤化物也可以通过连续的单电子氧化反应来合成。
