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在多功能生物反应器中使用硝化污泥同时氧化氨、对甲酚和硫化物:一种新颖的替代方法。

Simultaneous oxidation of ammonium, p-cresol and sulfide using a nitrifying sludge in a multipurpose bioreactor: a novel alternative.

机构信息

Universidad Autónoma Metropolitana-Iztapalapa, Departamento de Biotecnología, Mexico.

出版信息

Bioresour Technol. 2011 Feb;102(3):3623-5. doi: 10.1016/j.biortech.2010.10.127. Epub 2010 Nov 3.

DOI:10.1016/j.biortech.2010.10.127
PMID:21094042
Abstract

A nitrifying continuous stirred tank reactor was used as multipurpose bioreactor and it was operated for 325 days at 220 mg NH(4)(+)-N/Ld, 89 mg p-cresol-C /Ld and 36-76 mg S(2-)/Ld. The bioreactor was fed in sequential way, firstly with ammonium, achieving a consumption efficiency of 89%, with a nitrate yield of 0.99. Afterward, p-cresol was fed, achieving ammonium and p-cresol consumption efficiencies of 95% and 100%, respectively. The nitrate yield was higher and no aromatic intermediaries from p-cresol were detected. Finally sulfide was fed and the consumption efficiencies for all substrates were of 100%, being nitrate, HCO(3)(-) and sulfate the end products. The kinetic results showed that biological sulfide consumption was 13-fold faster than the chemical oxidation. This is the first time that a nitrifying reactor can be used for multiple purposes and also for the simultaneous removal of ammonium, sulfide and p-cresol in one step.

摘要

采用硝化连续搅拌槽式反应器作为多用途生物反应器,在 220mgNH(4)(+) - N/Ld、89mgp- 甲酚 - C/Ld 和 36-76mgS(2-)/Ld 的条件下运行 325 天。生物反应器采用顺序进料方式,首先进料氨,消耗效率为 89%,硝酸盐生成率为 0.99。随后,进料 p- 甲酚,实现了 95%的氨和 100%的 p- 甲酚消耗效率,同时没有检测到来自 p- 甲酚的芳香中间体。最后进料硫化物,所有底物的消耗效率均为 100%,最终产物为硝酸盐、HCO(3)(-)和硫酸盐。动力学结果表明,生物硫化物的消耗速度比化学氧化快 13 倍。这是首次利用硝化反应器实现多种用途,以及在一步同时去除氨、硫化物和 p- 甲酚。

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