Institute of Physics, Polish Academy of Sciences, Aleja Lotników 32/46, PL-02-668 Warszawa, Poland.
Nat Mater. 2010 Dec;9(12):965-74. doi: 10.1038/nmat2898. Epub 2010 Nov 23.
Over the past ten years, the search for compounds combining the properties of semiconductors and ferromagnets has evolved into an important field of materials science. This endeavour has been fuelled by many demonstrations of remarkable low-temperature functionalities in the ferromagnetic structures (Ga,Mn)As and p-(Cd,Mn)Te, and related compounds, and by the theoretical prediction that magnetically doped, p-type nitride and oxide semiconductors might support ferromagnetism mediated by valence-band holes to above room temperature. Indeed, ferromagnetic signatures persisting at high temperatures have been detected in a number of non-metallic systems, even under conditions in which the presence of spin ordering was not originally anticipated. Here I review recent experimental and theoretical developments, emphasizing that they not only disentangle many controversies and puzzles accumulated over the past decade but also offer new research prospects.
在过去的十年中,寻找同时具有半导体和铁磁性的化合物已经发展成为材料科学的一个重要领域。这种努力受到许多在铁磁结构(Ga,Mn)As 和 p-(Cd,Mn)Te 及相关化合物中低温功能的显著演示的推动,并且理论预测磁性掺杂的 p 型氮化物和氧化物半导体可能支持通过价带空穴介导的高于室温的铁磁性。实际上,在许多非金属系统中,即使在最初不预期自旋有序存在的情况下,也检测到在高温下仍然存在的铁磁特征。在这里,我回顾了最近的实验和理论进展,强调它们不仅解决了过去十年中积累的许多争议和难题,而且还提供了新的研究前景。