Centre d'Investigació en Nanociencia i Nanotecnologia (CIN2, ICN-CSIC), Esfera UAB, 08193 Bellaterra, Spain.
Chem Soc Rev. 2011 Jan;40(1):291-305. doi: 10.1039/c0cs00042f. Epub 2010 Nov 25.
Metal-organic materials are found to be a fascinating novel class of functional nanomaterials. The limitless combinations between inorganic and organic building blocks enable researchers to synthesize 0- and 1-D metal-organic discrete nanostructures with varied compositions, morphologies and sizes, fabricate 2-D metal-organic thin films and membranes, and even structure them on surfaces at the nanometre length scale. In this tutorial review, the synthetic methodologies for preparing these miniaturized materials as well as their potential properties and future applications are discussed. This review wants to offer a panoramic view of this embryonic class of nanoscale materials that will be of interest to a cross-section of researchers working in chemistry, physics, medicine, nanotechnology, materials chemistry, etc., in the next years.
金属有机材料被发现是一类非常有趣的新型功能纳米材料。无机和有机构筑块之间的无限组合使得研究人员能够合成具有不同组成、形貌和尺寸的 0-维和 1-维金属有机离散纳米结构，制造 2-维金属有机薄膜和膜，甚至在纳米尺度的表面上对它们进行结构设计。在本综述中，讨论了制备这些微型材料的合成方法以及它们潜在的性质和未来的应用。本综述旨在为这一新兴的纳米级材料领域提供一个全景，在未来几年内，将引起化学、物理、医学、纳米技术、材料化学等领域的众多研究人员的兴趣。
