Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1, Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan.
Chem Commun (Camb). 2011 Jan 28;47(4):1124-50. doi: 10.1039/c0cc02921a. Epub 2010 Nov 29.
Dynamic covalent functionality has been acknowledged as a powerful tool for the construction of organised architectures, the reversible nature thermodynamically facilitates self-control and self-correction. The use of boronic acids complexation with diols and their congeners has already shown great promise in realising and developing reversible boron-containing multicomponent systems with dynamic covalent functionality. The structure-directing potential has lead to the development of a variety of self-organisation involving not only macrocycles, cages and capsules, but also porous covalent organic frameworks and polymers. Structure controls as well as remarkable synthesis are highlighted in this feature article.
动态共价键功能已被公认为构建有序结构的有力工具，其热力学可逆性质有利于自我控制和自我修正。硼酸与二醇及其同系物的络合作用已经在实现和开发具有动态共价键功能的含硼多组分可逆体系方面显示出巨大的潜力。结构导向作用导致了各种自组装的发展，不仅涉及大环、笼和胶囊，还涉及多孔共价有机骨架和聚合物。本文重点介绍了结构控制和显著的合成。
