Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan.
Chem Commun (Camb). 2011 Feb 14;47(6):1875-7. doi: 10.1039/c0cc03149f. Epub 2010 Dec 2.
Oxidation of alcohols in the presence of a catalytic amount of fluorous IBX and Oxone as a co-oxidant resulted in the corresponding carbonyl compounds in good to high yields. The fluorous IBX is readily recovered as insoluble fluorous IBA from the reaction mixture by simple filtration, and can be reused without significant loss of the catalytic activity.
在催化量的全氟 IBX 和 Oxone 作为共氧化剂的存在下氧化醇，得到相应的羰基化合物，产率好至高产率。全氟 IBX 通过简单过滤从反应混合物中容易地以不溶性全氟 IBA 的形式回收，并可以在没有显著损失催化活性的情况下重复使用。
