锡介导的烯醇醚在水中的烯丙基化反应。
Tin mediated allylation reactions of enol ethers in water.
机构信息
Department of Chemistry, National Changhua University of Education, Changhua, Taiwan 50007.
出版信息
Org Lett. 2011 Jan 21;13(2):332-5. doi: 10.1021/ol102825t. Epub 2010 Dec 13.
PMID:21142089
Abstract
Under tin-mediated Barbier-type reaction conditions, hydration of enol ethers takes place to form aldehydes that undergo allylation reactions. By using this process, various homoallylic alcohols and 2-halohomoallylic alcohols are produced in good to excellent yields.
摘要
在锡介导的 Barbier 型反应条件下，烯醇醚发生水合反应形成醛，醛再发生烯丙基化反应。通过这种方法，可以以良好到优异的产率得到各种偕烯丙基醇和 2-卤代偕烯丙基醇。
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