Department of Chemistry, York University, 440 Chemistry Building, 4700 Keele Street, Toronto, ON, Canada M3J 1P3.
Org Lett. 2011 Jan 21;13(2):232-5. doi: 10.1021/ol1026415. Epub 2010 Dec 16.
A palladium-catalyzed tandem semipinacol rearrangement/direct arylation reaction using α-aryl isopropenyl-tert-cyclobutanols has been developed. This reaction gives access to benzodiquinanes in moderate to good yields and tolerates alkyl-, alkoxy-, and halogen-substituted aryl groups.
钯催化的串联半频哪醇重排/直接芳基化反应使用α-芳基异丙烯基叔环丁醇已经被开发出来。该反应以中等至良好的收率得到苯并二氢喹啉，并能耐受烷基、烷氧基和卤素取代的芳基。
