一种在水中高效的铜催化碳硫键形成的方法。
An efficient copper-catalyzed carbon-sulfur bond formation protocol in water.
机构信息
Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610041, China.
出版信息
Org Lett. 2011 Feb 4;13(3):454-7. doi: 10.1021/ol102784c. Epub 2010 Dec 21.
PMID:21174396
Abstract
An efficient protocol of copper-catalyzed C-S bond formation between aryl halides and potassium thiocyanate leading to diaryl sulfides is reported. A variety of diaryl sulfides can be synthesized in good to excellent yields up to 94%.
摘要
报道了一种高效的铜催化芳基卤化物与硫氰酸钾形成 C-S 键的反应协议，可得到二芳基硫醚。多种二芳基硫醚可以以良好至优异的收率（高达 94%）合成。
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