Lorenzini Fabio, Patrick Brian O, James Brian R
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada.
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m179-80. doi: 10.1107/S1600536807065877.
The title compound, [RhCl(C(14)H(15)P)(2)(CO)], crystallizes with two almost identical mol-ecules in the asymmetric unit. The mol-ecules have the Rh(I) atom in a square-planar geometry. The crystal structure involves intermolecular C-H⋯O hydrogen bonds.
标题化合物[RhCl(C₁₄H₁₅P)₂(CO)]在不对称单元中结晶出两个几乎相同的分子。这些分子中的Rh(I)原子呈平面正方形几何构型。晶体结构包含分子间C—H⋯O氢键。