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反式-羰基二氯双(乙基二苯基膦-κP)铑(I)

trans-Carbonyl-chloridobis(ethyl-diphenyl-phosphine-κP)rhodium(I).

作者信息

Lorenzini Fabio, Patrick Brian O, James Brian R

机构信息

Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m179-80. doi: 10.1107/S1600536807065877.

DOI:10.1107/S1600536807065877
PMID:21200527
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915114/
Abstract

The title compound, [RhCl(C(14)H(15)P)(2)(CO)], crystallizes with two almost identical mol-ecules in the asymmetric unit. The mol-ecules have the Rh(I) atom in a square-planar geometry. The crystal structure involves intermolecular C-H⋯O hydrogen bonds.

摘要

标题化合物[RhCl(C₁₄H₁₅P)₂(CO)]在不对称单元中结晶出两个几乎相同的分子。这些分子中的Rh(I)原子呈平面正方形几何构型。晶体结构包含分子间C—H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15ee/2915114/b6f3ae694496/e-64-0m179-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15ee/2915114/b6f3ae694496/e-64-0m179-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/15ee/2915114/b6f3ae694496/e-64-0m179-fig1.jpg

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本文引用的文献

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Dalton Trans. 2007 Aug 14(30):3224-6. doi: 10.1039/b706691k. Epub 2007 Jun 25.
2
Formation of a phosphine-phosphinite ligand in RhCl(PRR'2)[P,P-R'(R)POCH2P(CH2OH)2] and R'H from cis-RhCl(PRR'2)2[P(CH2OH)3] via P-C bond cleavage.
Inorg Chem. 2007 Oct 15;46(21):8998-9002. doi: 10.1021/ic7012182. Epub 2007 Sep 15.
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Water-soluble hydroxyalkylated phosphines: examples of their differing behaviour toward ruthenium and rhodium.水溶性羟烷基化膦:它们对钌和铑不同反应的实例。
Dalton Trans. 2004 Dec 21(24):4202-8. doi: 10.1039/b411701h. Epub 2004 Nov 16.