μ-乙酸根-κO:O'-[7,23-二苄基-15,31-二氯-3,7,11,19,23,27-六氮杂三环-[27.3.1.1]三十四-1(32),2,11,13,15,17(34),18,27,29(33),30-癸烯-33,34-二醇根-κN,N,N,O,O:N,N,N,O,O]二镍(II)高氯酸盐乙腈溶剂化物
μ-Acetato-κO:O'-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa-azatri-cyclo-[27.3.1.1]tetra-triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca-ene-33,34-diolato-κN,N,N,O,O:N,N,N,O,O]dinickel(II) per-chlorate acetonitrile disolvate.
作者信息
Kong Juan, Zhou Hong, Pan Zhi-Quan
机构信息
Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430073, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m18. doi: 10.1107/S1600536807061399.
The title complex, [Ni(2)(C(42)H(46)Cl(2)N(6)O(2))(C(2)H(3)O(2))]ClO(4)·2CH(3)CN, was synthesized by condensation of 2,6-diformyl-4-chloro-phenol with N,N-bis-(amino-prop-yl)benzyl-amine in the presence of Ni(II) ions. The ligand is a 28-membered macrocycle with two identical pendant arms. The coordination geometries of the Ni atoms are both octa-hedral. The two Ni atoms are bridged by two phenolate O atoms of the macrocyclic ligand and one acetate ligand, with an Ni⋯Ni distance of 3.147 (4) Å.
标题配合物[Ni₂(C₄₂H₄₆Cl₂N₆O₂)(C₂H₃O₂)]ClO₄·2CH₃CN是通过2,6 - 二甲酰基 - 4 - 氯苯酚与N,N - 双(氨基丙基)苄胺在Ni(II)离子存在下缩合而成的。配体是一个具有两个相同侧臂的28元大环。Ni原子的配位几何构型均为八面体。两个Ni原子由大环配体的两个酚盐O原子和一个乙酸盐配体桥联，Ni⋯Ni距离为3.147(4) Å。
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