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[μ-10,22-Dichloro-3,6-bis-(2-furylmeth-yl)-3,6,14,18-tetra-azatricyclo-[18.3.1.1]penta-cosa-1(23),8,10,12(25),13,18,20(24),21-octa-ene-24,25-diolato-κN,N,O,O:N,N,O:O]bis-[chloridocopper(II)] acetonitrile solvate.

作者信息

Chen Chen, Cheng Yu, Liu Pan, Zhou Hong, Pan Zhi-Quan

机构信息

Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m162. doi: 10.1107/S1600536809000166.

Abstract

The title compound, [Cu(2)(C(31)H(30)Cl(2)N(4)O(4))Cl(2)]·CH(3)CN, was synthesized by cyclo-condensation between N,N'-bis-(2-fur-yl)-N,N'-bis-(3-formyl-5-chloro-salicylaldehyde)ethyl-enediamine and 1,3-diamino-propane in the presence of Cu(II) ions. It is an unsymmetrical dinuclear Cu(II) complex. The coordination geometry for each Cu(II) atom can be discribed as distorted square-pyramidal. The two Cu atoms are bridged by two phenolate O atoms with a Cu⋯Cu distance of 3.0274 (9) Å.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4736/2968155/4f7f926cc5c4/e-65-0m162-fig1.jpg

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