μ-10,21-二甲基-3,6,14,17-四氮杂三环-[17.3.1.1]二十四碳-1(23),8(24),9,11,19,21-六烯-23,24-二醇根合-κN,N,O,O:N,N,O,O]双[(硝酸根-κO,O')镍(II)]
μ-10,21-Dimethyl-3,6,14,17-tetra-aza-tricyclo-[17.3.1.1]tetra-cosa-1(23),8(24),9,11,19,21-hexa-ene-23,24-diolato-κN,N,O,O:N,N,O,O]bis-[(nitrato-κO,O')nickel(II).
作者信息
Li Quan-Jun, Ma Jian-Fang, Liu Jie, Han Ting-Ting
机构信息
Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 18;65(Pt 5):m522. doi: 10.1107/S1600536809010174.
In the title centrosymmetric dinuclear nickel complex, [Ni(2)(C(22)H(30)N(4)O(2))(NO(3))(2)], each of the two Ni(II) atoms has a distorted octa-hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion. The two Ni atoms are bridged by two phenolate O atoms, forming a four-membered Ni(2)O(2) ring.
在标题为中心对称双核镍配合物[Ni₂(C₂₂H₃₀N₄O₂)(NO₃)₂]中，两个Ni(II)原子中的每一个都具有扭曲的八面体几何构型，由大环配体的两个N原子和两个O原子以及一个螯合硝酸根阴离子的两个O原子界定。两个Ni原子由两个酚盐O原子桥连，形成一个四元Ni₂O₂环。
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