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链状聚[[四水合-(μ-4,4'-联吡啶-κN:N')锌(II)]富马酸四水合物]

catena-Poly[[tetra-aqua-(μ-4,4'-bipyridine-κN:N')zinc(II)] fumarate tetra-hydrate].

作者信息

Tian Yong, Wu Ya-Pan, Li Dong-Sheng, Wang Hui, Wang Ji-Wu

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 16;64(Pt 5):m662-3. doi: 10.1107/S1600536808009227.

DOI:10.1107/S1600536808009227
PMID:21202206
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961133/
Abstract

In the title compound, {Zn(C(10)H(8)N(2))(H(2)O)(4)·4H(2)O}(n), the Zn(II) atom is coordinated by two N atoms from two μ-4,4'-bipyridine ligands and four water mol-ecules in a distorted octa-hedral geometry. The coordination unit is extended through the Zn-N bond, leading to a one-dimensional cationic chain. A twofold rotation axis passes through the Zn atom and along the axis of the 4,4'-bipyridine ligand. Each uncoordinated water mol-ecule acts as both hydrogen-bond donor and acceptor. A three-dimensional network is constructed through hydrogen bonds involving water mol-ecules and fumarate dianions.

摘要

在标题化合物{Zn(C₁₀H₈N₂)(H₂O)₄·4H₂O}ₙ中，Zn(II)原子由来自两个μ - 4,4'-联吡啶配体的两个N原子和四个水分子以扭曲的八面体几何构型配位。配位单元通过Zn - N键延伸，形成一维阳离子链。一个二重旋转轴穿过Zn原子并沿着4,4'-联吡啶配体的轴。每个未配位的水分子既作为氢键供体又作为氢键受体。通过涉及水分子和富马酸二阴离子的氢键构建了三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/79ea/2961133/739bc6861cfc/e-64-0m662-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/79ea/2961133/e1e958b713e7/e-64-0m662-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/79ea/2961133/739bc6861cfc/e-64-0m662-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/79ea/2961133/e1e958b713e7/e-64-0m662-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/79ea/2961133/739bc6861cfc/e-64-0m662-fig2.jpg

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