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聚[八-μ-水-四水-双(μ-5-磺酸基苯-1,3-二羧基合)钴(II)四钠]

Poly[octa-μ-aqua-tetra-aqua-bis(μ-5-sul-fon-atobenzene-1,3-dicarboxyl-ato)cobalt(II)tetra-sodium].

作者信息

Zhang Bing-Yu, Nie Jing-Jing, Xu Duan-Jun

机构信息

Department of Chemistry, Zhejiang University, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 11;65(Pt 4):m387-8. doi: 10.1107/S1600536809008174.

DOI:10.1107/S1600536809008174
PMID:21582338
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968916/
Abstract

The title compound, CoNa(4)(C(8)H(3)O(7)S)(2)(H(2)O)(12), is a three-dimensional coordination polymer bridged by sulfoisophthalate trianions and water mol-ecules. The Co(II) atom, located on an inversion centre, is coordinated by two carboxyl-ate groups of the sulfoisophthalate trianions and by four water mol-ecules in a distorted CoO(6) octa-hedral geometry. Two independent Na(I) atoms also have a distorted octa-hedral coordination geometry formed by water, carboxyl-ate O and sulfonate O atoms. An extensive O-H⋯O and C-H⋯O hydrogen-bonding network is present in the crystal structure, as well as weak π-π stacking [centroid-centroid distance = 3.9553 (11) Å].

摘要

标题化合物[CoNa₄(C₈H₃O₇S)₂(H₂O)₁₂]ₙ是一种由磺基间苯二甲酸三阴离子和水分子桥连的三维配位聚合物。位于对称中心的Co(II)原子由磺基间苯二甲酸三阴离子的两个羧酸根基团和四个水分子配位，呈扭曲的CoO₆八面体几何构型。两个独立的Na(I)原子也具有由水、羧酸根O和磺酸根O原子形成的扭曲八面体配位几何构型。晶体结构中存在广泛的O—H⋯O和C—H⋯O氢键网络，以及弱的π - π堆积作用[质心 - 质心距离 = 3.9553 (11) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cc6f/2968916/8907b6bde514/e-65-0m387-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cc6f/2968916/69edded132f6/e-65-0m387-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cc6f/2968916/8907b6bde514/e-65-0m387-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cc6f/2968916/69edded132f6/e-65-0m387-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cc6f/2968916/8907b6bde514/e-65-0m387-fig2.jpg

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2
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3
Catena-poly[[[aquabis(1H-benzimidazole-kappaN(3))cadmium(II)]-micro-phthalato-kappa(3)O,O':O"] hemihydrate].
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4
Nobel lecture. The photosynthetic reaction centre from the purple bacterium Rhodopseudomonas viridis.诺贝尔演讲。来自绿色红假单胞菌的光合反应中心。
EMBO J. 1989 Aug;8(8):2149-70. doi: 10.1002/j.1460-2075.1989.tb08338.x.