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链状聚[[[二碘镉（II）]-μ-1-（4-吡啶甲基）-1H-苯并咪唑]甲醇半溶剂化物]

catena-Poly[[[diiodidocadmium(II)]-μ-1-(4-pyridylmeth-yl)-1H-benzimidazole] methanol hemisolvate].

作者信息

Wang Jun-Jie, Yan Li-Fan, Hu Tong-Liang

机构信息

Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m200. doi: 10.1107/S1600536807061302.

DOI:10.1107/S1600536807061302
PMID:21200548
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915130/
Abstract

In the title coordination polymer, {[CdI(2)(C(13)H(11)N(3))]·0.5CH(4)O}(n), each Cd(II) center is four-coordinated by two N-atom donors from two 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two iodide anions, forming a tetra-hedral coordination geometry. L ligands bridge adjacent Cd(II) ions, generating two crystallographically independent approximately orthogonal one-dimensional chains. The methanol solvent mol-ecule associates with one of the chains via O-H⋯I inter-actions.

摘要

在标题配位聚合物{[CdI₂(C₁₃H₁₁N₃)]·0.5CH₄O}ₙ中，每个Cd(II)中心由来自两个1-(4-吡啶甲基)-1H-苯并咪唑(L)配体的两个N原子供体和两个碘阴离子进行四配位，形成四面体配位几何结构。L配体桥连相邻的Cd(II)离子，生成两条晶体学上独立的近似正交的一维链。甲醇溶剂分子通过O—H⋯I相互作用与其中一条链缔合。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dad/2915130/125415ea0d28/e-64-0m200-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dad/2915130/c5e5d4cd0321/e-64-0m200-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dad/2915130/cdd79ccce2b2/e-64-0m200-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dad/2915130/125415ea0d28/e-64-0m200-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dad/2915130/c5e5d4cd0321/e-64-0m200-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dad/2915130/cdd79ccce2b2/e-64-0m200-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1dad/2915130/125415ea0d28/e-64-0m200-fig3.jpg

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本文引用的文献

1
Ligand design in multimetallic architectures: six lessons learned.多金属结构中的配体设计：六点经验教训
Acc Chem Res. 2005 Apr;38(4):243-50. doi: 10.1021/ar040166v.