catena-Poly[[[diiodidocadmium(II)]-μ-1-(4-pyridylmeth-yl)-1H-benzimidazole] methanol hemisolvate].
作者信息
Wang Jun-Jie, Yan Li-Fan, Hu Tong-Liang
机构信息
Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m200. doi: 10.1107/S1600536807061302.
Abstract
In the title coordination polymer, {[CdI(2)(C(13)H(11)N(3))]·0.5CH(4)O}(n), each Cd(II) center is four-coordinated by two N-atom donors from two 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two iodide anions, forming a tetra-hedral coordination geometry. L ligands bridge adjacent Cd(II) ions, generating two crystallographically independent approximately orthogonal one-dimensional chains. The methanol solvent mol-ecule associates with one of the chains via O-H⋯I inter-actions.
摘要
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本文引用的文献
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Ligand design in multimetallic architectures: six lessons learned.多金属结构中的配体设计：六点经验教训
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