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catena-Poly[[diiodidocadmium(II)]-μ-4,4'-di-4-pyridyl-2,2'-disulfanediyldipyrimidine].链状聚[[二碘镉（II）]-μ-4,4'-二-4-吡啶基-2,2'-二硫二基二嘧啶]
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2
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catena-Poly[[di-μ-iodido-dicopper(I)(Cu-Cu)]bis-(μ-4,4'-di-3-pyridyl-2,2'-disulfanediyldipyrimidine)].链状聚[[双-μ-碘代-二铜（I）（铜-铜）]双-（μ-4,4'-二-3-吡啶基-2,2'-二硫代二嘧啶）]
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catena-Poly[[diiodidocadmium]-μ-[4,4'-(2,3,5,6-tetra-methyl-1,4-phenyl-ene)bis-(methyl-ene)]bis-(3,5-dimethyl-1H-pyrazole)-κN:N].链状聚[[二碘镉]-μ-[4,4'-(2,3,5,6-四甲基-1,4-亚苯基)双-(亚甲基)]双-(3,5-二甲基-1H-吡唑)-κN:N]
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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.

链状聚[[二碘镉（II）]-μ-4,4'-二-4-吡啶基-2,2'-二硫二基二嘧啶]

catena-Poly[[diiodidocadmium(II)]-μ-4,4'-di-4-pyridyl-2,2'-disulfanediyldipyrimidine].

作者信息

Zhu Hai-Bin

机构信息

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China, and School of Material Science and Engineering, Southeast University, Nanjing 211189, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):m1. doi: 10.1107/S1600536809051162.

DOI:10.1107/S1600536809051162
PMID:21579907
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980057/
Abstract

In the title compound, CdI(2)(C(18)H(12)N(6)S(2)), the 4,4'-di-4-pyridyl-2,2'-disulfanediyldipyrimidine (L) ligand bridges two Cd(II) centers, forming polymeric zigzag chains extending along the b axis. The Cd(II) ions are coordinated by two N atoms from two L ligands and two iodide anions in a distorted tetra-hedral geometry.

摘要

在标题化合物[CdI₂(C₁₈H₁₂N₆S₂)]ₙ中，4,4'-二（4-吡啶基）-2,2'-二硫二基二嘧啶（L）配体连接两个Cd(II)中心，形成沿b轴延伸的聚合之字形链。Cd(II)离子由来自两个L配体的两个N原子和两个碘离子以扭曲的四面体几何构型配位。