• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双[2-(苄基亚氨基甲基)-4-氯苯酚根-κN,O]镍(II)

Bis[2-(benzyl-imino-meth-yl)-4-chloro-phenolato-κN,O]nickel(II).

作者信息

Li Zong-Xiao, Zhang Xin-Li, Pu Xiao-Hua

机构信息

Department of Chemistry, Baoji University of Arts and Science, Baoji, Shaanxi 721007, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m202. doi: 10.1107/S1600536807054943.

DOI:10.1107/S1600536807054943
PMID:21200550
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915132/
Abstract

In the mononuclear centrosymmetric title compound, [Ni(C(14)H(11)ClNO)(2)], the Ni(II) atom, lying on a center of symmetry, is four-coordinated by two O atoms and two N atoms from two Schiff base ligands, forming a slightly distorted square-planar environment. The dihedral angle between the two aromatic rings of the ligand is 72.0 (2)°. No significant hydrogen bonding or π-π stacking inter-actions are observed.

摘要

在单核中心对称的标题化合物[Ni(C₁₄H₁₁ClNO)₂]中，位于对称中心的Ni(II)原子由两个席夫碱配体的两个O原子和两个N原子进行四配位，形成略微扭曲的平面正方形环境。配体的两个芳香环之间的二面角为72.0 (2)°。未观察到明显的氢键或π-π堆积相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3d7/2915132/d3f0afd73940/e-64-0m202-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3d7/2915132/16796eaa27c9/e-64-0m202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3d7/2915132/d3f0afd73940/e-64-0m202-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3d7/2915132/16796eaa27c9/e-64-0m202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3d7/2915132/d3f0afd73940/e-64-0m202-fig2.jpg

相似文献

1
Bis[2-(benzyl-imino-meth-yl)-4-chloro-phenolato-κN,O]nickel(II).双[2-(苄基亚氨基甲基)-4-氯苯酚根-κN,O]镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m202. doi: 10.1107/S1600536807054943.
2
Bis{2-[(E)-benzyl-imino-meth-yl]-4-methyl-phenolato-κN,O}nickel(II).双{2-[(E)-苄基亚氨基甲基]-4-甲基苯酚根-κN,O}镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 15;65(Pt 8):m923. doi: 10.1107/S1600536809026658.
3
Bis{2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolato-κ(2)N,O(1)}nickel(II).双{2-[亚氨基-(苯基)甲基]-5-甲氧基苯酚根-κ(2)N,O(1)}镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1387. doi: 10.1107/S1600536812043061. Epub 2012 Oct 20.
4
Bis{(E)-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]-6-meth-oxy-phenolato-κN,O}copper(II).双{（E）-2-[(2-氯-3-吡啶基)亚氨基甲基]-6-甲氧基苯酚根-κN,O}铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 18;67(Pt 1):m91. doi: 10.1107/S1600536810052414.
5
Bis[4-chloro-2-(imino-meth-yl)phenolato]copper(II).双[4-氯-2-(亚氨基甲基)苯酚根合]铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):m369. doi: 10.1107/S1600536809007624.
6
Bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]-6-methoxy-phenolato-κN,N',O}nickel(II).双{2-[3-(二甲基氨基)丙基亚氨基甲基]-6-甲氧基苯酚根-κN,N',O}镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 9;64(Pt 8):m1009. doi: 10.1107/S1600536808020497.
7
Bis[(E)-4-bromo-2-(methoxy-imino-meth-yl)phenolato-κN,O]copper(II).双[(E)-4-溴-2-(甲氧基亚氨基甲基)苯酚根-κN,O]铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 18;65(Pt 12):m1599. doi: 10.1107/S1600536809047989.
8
Bis{2-meth-oxy-6-[3-(methyl-amino)propyl-imino-meth-yl]phenolato}nickel(II) bis-(perchlorate).双{2-甲氧基-6-[3-(甲氨基)丙基亚氨基甲基]苯酚根合}镍(II) 双(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 10;64(Pt 5):m646-7. doi: 10.1107/S1600536808009562.
9
Bis{(E)-4-bromo-2-[(2-chloro-3-pyrid-yl)imino-meth-yl]phenolato-κN,O}copper(II).双{（E）-4-溴-2-[(2-氯-3-吡啶基)亚氨基甲基]苯酚根-κN,O}铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m945. doi: 10.1107/S1600536809027792.
10
Bis[2-(cyclo-pentyl-imino-meth-yl)-5-meth-oxy-phenolato]copper(II).双[2-(环戊基亚氨基甲基)-5-甲氧基苯酚根]铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 3;66(Pt 8):m881. doi: 10.1107/S1600536810025481.

引用本文的文献

1
Synthesis and characterisation of κ-,-oxazoline-enolate complexes of nickel(ii): explorations in coordination chemistry and metal-mediated polymerisation.镍（II）的κ-恶唑啉烯醇盐配合物的合成与表征：配位化学与金属介导聚合反应的探索
RSC Adv. 2019 Jan 29;9(7):3956-3964. doi: 10.1039/c8ra10304f. eCollection 2019 Jan 25.

本文引用的文献

1
Synthesis, crystal structures, and nonlinear optical (NLO) properties of new Schiff-base nickel(II) complexes. Toward a new type of molecular switch?新型席夫碱镍（II）配合物的合成、晶体结构及非线性光学（NLO）性质。迈向新型分子开关？
Inorg Chem. 2005 Mar 21;44(6):1973-82. doi: 10.1021/ic048578n.
2
Tsalen- and Tsalpn-Based Nickel Complexes with Two Aldehyde Functionalities as Potential Synthons for Thiophenolate-Containing Di- and Polynucleating Acyclic and Macrocyclic Ligands.
Inorg Chem. 1997 Dec 17;36(26):6080-6085. doi: 10.1021/ic970713r.