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双[4-氯-2-(亚氨基甲基)苯酚根合]铜(II)

Bis[4-chloro-2-(imino-meth-yl)phenolato]copper(II).

作者信息

Tang Chunbao

机构信息

Department of Chemistry, Jiaying University, Meizhou 514015, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):m369. doi: 10.1107/S1600536809007624.

DOI:10.1107/S1600536809007624
PMID:21582324
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968960/
Abstract

In the title mononuclear copper(II) complex, [Cu(C(7)H(5)ClNO)(2)], the Cu atom, situated on an inversion center, is four-coordinated, in a slightly distorted square-planar geometry, by the N- and O-donor atoms of two symmetry-related 4-chloro-2-(imino-meth-yl)phenolate Schiff base ligands.

摘要

在标题单核铜（II）配合物[Cu(C₇H₅ClNO)₂]中，位于对称中心的Cu原子通过两个对称相关的4-氯-2-（亚氨基甲基）酚盐席夫碱配体的N和O供体原子进行四配位，呈略微扭曲的平面正方形几何构型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d4/2968960/61d00748214c/e-65-0m369-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d4/2968960/61d00748214c/e-65-0m369-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d7d4/2968960/61d00748214c/e-65-0m369-fig1.jpg

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本文引用的文献

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2
catena-Poly[[[N,N'-bis-(3-methoxy-benzyl-idene)ethyl-enediamine]copper(I)]-μ-thio-cyanato-κN:S].链状聚[[[N,N'-双-(3-甲氧基-亚苄基)乙二胺]铜(I)]-μ-硫氰酸根合-κN:S]
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 13;65(Pt 1):m70. doi: 10.1107/S1600536808041925.
3
Bis{2-meth-oxy-6-[(3-methoxy-prop-yl)imino-meth-yl]phenolato-κN,O}copper(II).
双{2-甲氧基-6-[(3-甲氧基丙基)亚氨基甲基]苯酚根-κN,O}铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1497. doi: 10.1107/S1600536808035289.
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The cocrystal μ-oxalato-κO,O:O,O-bis-(aqua-(nitrato-κO){[1-(2-pyridyl-κN)eth-ylidene]hydrazine-κN}copper(II)) μ-oxalato-κO,O:O,O-bis-((methanol-κO)(nitrato-κO){[1-(2-pyridyl-κN)eth-ylidene]hydrazine-κN}copper(II)) (1/1).共晶体μ-草酸根-κO,O:O,O-双（水合（硝酸根-κO）{[1-（2-吡啶基-κN）亚乙基]肼-κN}铜（II））μ-草酸根-κO,O:O,O-双（（甲醇-κO）（硝酸根-κO）{[1-（2-吡啶基-κN）亚乙基]肼-κN}铜（II））（1/1）
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.