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双{2-[(E)-苄基亚氨基甲基]-4-甲基苯酚根-κN,O}镍(II)

Bis{2-[(E)-benzyl-imino-meth-yl]-4-methyl-phenolato-κN,O}nickel(II).

作者信息

Chen Su-Zhen, Xia Dong-Guo

机构信息

State Key Laboratory Base of Novel Functional Materials and Preparation Science, Institute of Solid Materials Chemistry, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 15;65(Pt 8):m923. doi: 10.1107/S1600536809026658.

DOI:10.1107/S1600536809026658
PMID:21583379
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977259/
Abstract

In the title complex, [Ni(C(15)H(14)NO)(2)], the Ni(II) atom is located on an inversion centre and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a slightly distorted square-planar geometry. The phenyl and benzene rings in the ligand mol-ecule form a dihedral angle of 72.79 (8)°.

摘要

在标题配合物[Ni(C₁₅H₁₄NO)₂]中，Ni(II)原子位于一个反演中心，由来自两个对称相关的双齿席夫碱配体的两个O原子和两个N原子配位，形成略微扭曲的平面正方形几何构型。配体分子中的苯基和苯环形成72.79 (8)°的二面角。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cc/2977259/c70866153cb6/e-65-0m923-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cc/2977259/c70866153cb6/e-65-0m923-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cc/2977259/c70866153cb6/e-65-0m923-fig1.jpg

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