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1'-甲基-4'-(1-萘基)-3''-(1-萘基亚甲基)苊-1-螺-2'-吡咯烷-3'-螺-1''-环己烷-2,2''-二酮

1'-Methyl-4'-(1-naphth-yl)-3''-(1-naphthyl-methyl-ene)acenaphthene-1-spiro-2'-pyrrolidine-3'-spiro-1''-cyclo-hexane-2,2''-dione.

作者信息

Athimoolam S, Radha V Anu, Bahadur S Asath, Kumar R Ranjith, Perumal S

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o95-6. doi: 10.1107/S1600536807061387.

DOI:10.1107/S1600536807061387
PMID:21200972
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915050/
Abstract

In the title compound, C(42)H(33)NO(2), the six-membered cyclo-hexa-none ring adopts a slightly distorted chair conformation and the five-membered pyrrolidine ring is in an envelope conformation. The mol-ecular structure features four intra-molecular C-H⋯O inter-actions and an intra-molecular C-H⋯π inter-action. Furthermore, the crystal packing is stabilized by an inter-molecular C-H⋯O and three inter-molecular C-H⋯π inter-actions.

摘要

在标题化合物C(42)H(33)NO(2)中，六元环己酮环呈轻微扭曲的椅式构象，五元吡咯烷环呈信封式构象。分子结构具有四个分子内C-H⋯O相互作用和一个分子内C-H⋯π相互作用。此外，晶体堆积通过一个分子间C-H⋯O和三个分子间C-H⋯π相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c939/2915050/cac8d5deb08e/e-64-00o95-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c939/2915050/5f0b66e54e0e/e-64-00o95-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c939/2915050/cac8d5deb08e/e-64-00o95-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c939/2915050/5f0b66e54e0e/e-64-00o95-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c939/2915050/cac8d5deb08e/e-64-00o95-fig2.jpg

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