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5''-(4-氯-亚苄基)-1',1''-二甲基-3'-苯基-苊烯-1-螺-2'-吡咯烷-3'-螺-3''-吡啶-2,4''-二酮

5''-(4-Chloro-benzyl-idene)-1',1''-dimethyl-3'-phenyl-acenaphthene-1-spiro-2'-pyrrolidine-3'-spiro-3''-pyridine-2,4''-dione.

作者信息

Pandiarajan S, Saravanamoorthy S N, Kumar B Ravi, Kumar R Ranjith, Athimoolam S

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o99-o100. doi: 10.1107/S1600536807059582.

DOI:10.1107/S1600536807059582
PMID:21200975
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915053/
Abstract

In the title compound, C(34)H(28)Cl(2)N(2)O(2), the five-membered pyrrolidine ring adopts an envelope conformation and the six-membered piperidinone ring is in a distorted half-chair conformation. The mol-ecular structure shows three intra-molecular C-H⋯O inter-actions and the crystal packing is stabilized through inter-molecular C-H⋯O and C-H⋯π inter-actions.

摘要

在标题化合物C(34)H(28)Cl(2)N(2)O(2)中，五元吡咯烷环呈信封构象，六元哌啶酮环处于扭曲的半椅构象。分子结构显示有三个分子内C—H⋯O相互作用，晶体堆积通过分子间C—H⋯O和C—H⋯π相互作用得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c811/2915053/534d856e7d60/e-64-00o99-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c811/2915053/ef35365c9ee0/e-64-00o99-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c811/2915053/534d856e7d60/e-64-00o99-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c811/2915053/ef35365c9ee0/e-64-00o99-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c811/2915053/534d856e7d60/e-64-00o99-fig2.jpg

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