（1H-咪唑-κN）{N-[1-（2-氧代苯基-κO）亚乙基]-L-苯基丙氨酸根-κN，O}铜（II）
(1H-Imidazole-κN) {N-[1-(2-oxidophenyl-κO)ethyl-idene]-l-phenyl-alaninato-κN,O}copper(II).
作者信息
Han Yong-Jun, Zhao Gan-Qing, Zhao Xiao-Jun, Song Wen-Li, Shi Jie-Li
机构信息
School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):m1228. doi: 10.1107/S160053680802758X.
Abstract
In the title compound, [Cu(C(17)H(15)NO(3))(C(3)H(4)N(2))], the Cu(II) atom is four-coordinated by two O atoms and the N atom of the tridentate Schiff base ligand, and one N atom from the imidazole ligand in a distorted square-planar geometry. In the crystal structure, mol-ecules are linked into dimers by inter-molecular N-H⋯O hydrogen bonds.
摘要
在标题化合物[Cu(C₁₇H₁₅NO₃)(C₃H₄N₂)]中，Cu(II)原子由三齿席夫碱配体的两个O原子和N原子以及咪唑配体的一个N原子以扭曲的平面正方形几何构型进行四配位。在晶体结构中，分子通过分子间的N—H⋯O氢键连接成二聚体。
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