（咪唑-κN）{N-[1-(2-氧代苯基)亚乙基]-L-缬氨酸根-κO,N,O'}铜（II）
(Imidazole-κN){N-[1-(2-oxidophenyl)ethylidene]-l-valinato-κO,N,O'}copper(II).
作者信息
Zhao Gan-Qing, Liu Qiao-Ru, Yang Wei-Chun, Li Song-Tian, Wang Xiang
机构信息
School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 6;64(Pt 10):m1250-1. doi: 10.1107/S1600536808028134.
In each of the two independent mol-ecules in the asymmetric unit of the title compound, [Cu(C(13)H(15)NO(3))(C(3)H(4)N(2))], the Cu(II) atom is four-coordinated by two O atoms and the N atom of the tridentate Schiff base ligand and one N atom from the imidazole ligand in a distorted square-planar geometry. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds.
在标题化合物[Cu(C₁₃H₁₅NO₃)(C₃H₄N₂)]的不对称单元中的两个独立分子中，每个分子里的Cu(II)原子通过两个O原子、三齿席夫碱配体的N原子以及咪唑配体的一个N原子以扭曲的平面正方形几何构型进行四配位。在晶体结构中，分子通过分子间N—H⋯O氢键相连。
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