Li Jinghong, Guo Zhenghua, Li Lianzhi, Wang Daqi
School of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 10;66(Pt 5):m516. doi: 10.1107/S1600536810012675.
In the title complex, [Cu(C(14)H(11)NO(4))(C(12)H(8)N(2))], the tridentate Schiff base ligand is derived from the condensation of 2-hydr-oxy-1-naphthaldehyde and l-serine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of inter-molecular O-H⋯O and C-H⋯O hydrogen bonds results in a two-dimensional network structure parallel to (001).
在标题配合物[Cu(C₁₄H₁₁NO₄)(C₁₂H₈N₂)]中，三齿席夫碱配体由2-羟基-1-萘甲醛与L-丝氨酸缩合而成。Cu(II)原子由席夫碱配体的一个N原子和两个O原子以及1,10-菲咯啉配体的两个N原子以扭曲的四方锥几何构型进行五配位。在晶体结构中，分子间的O—H⋯O和C—H⋯O氢键相结合，形成了平行于(001)的二维网络结构。
