链状聚[[双（吡啶-κN）镍（II）]-μ-草酸根-κO，O：O，O]
catena-Poly[[bis-(pyridine-κN)nickel(II)]-μ-oxalato-κO,O:O,O].
作者信息
Xuan Zhen-Yu, Che Yong, Huang Yong-Chun
机构信息
Department of Laboratory and Equipment Management, Yanbian University, Yanbian 133002, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 19;64(Pt 8):m1040. doi: 10.1107/S1600536808021703.
The title compound, Ni(C(2)O(4))(C(5)H(5)N)(2), was synthesized under hydro-(solvo)thermal conditions. The Ni(II) atom, lying on a twofold rotation axis, has an octa-hedral coordination geometry involving two N atoms from two pyridine ligands and four O atoms from two oxalate ligands. The Ni atoms are connected by the tetra-dentate bridging oxalate ligands into a one-dimensional zigzag chain.
标题化合物[Ni(C₂O₄)(C₅H₅N)₂]ₙ是在水（溶剂）热条件下合成的。位于二重旋转轴上的Ni(II)原子具有八面体配位几何构型，涉及来自两个吡啶配体的两个N原子和来自两个草酸根配体的四个O原子。Ni原子通过四齿桥连草酸根配体连接成一维锯齿链。
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