• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[双-[2-氯-6-(1H-1,2,4-三唑-1-基-κN)吡啶]镉(II)]-二-μ-硫氰酸根-κN:S;κS:N]：一种一维配位聚合物。

catena-Poly[[bis-[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN)pyridine]cadmium(II)]-di-μ-thio-cyanato-κN:S;κS:N]: a one-dimensional coordination polymer.

作者信息

Yang Zhong Nian, Sun Ting Ting

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 27;64(Pt 10):m1327. doi: 10.1107/S1600536808030547.

DOI:10.1107/S1600536808030547
PMID:21201062
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959435/
Abstract

In the crystal structure of the title complex, Cd(NCS)(2)(C(7)H(5)ClN(4))(2), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octa-hedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine mol-ecule acts as a terminal ligand. The thio-cyanate ligands function as μ(1,3)-bridging units connecting adjacent Cd(II) atoms with a separation of 5.7525 (11) Å, forming a one-dimensional chain along the a axis.

摘要

在标题配合物Cd(NCS)(2)(C(7)H(5)ClN(4))(2)的晶体结构中，Cd(II)原子位于一个晶体学倒转中心上，并呈现出扭曲的八面体几何构型。2-氯-6-(1H-1,2,4-三唑-1-基)吡啶分子作为末端配体。硫氰酸根配体作为μ(1,3)-桥连单元，以5.7525 (11) Å的间距连接相邻的Cd(II)原子，沿a轴形成一维链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a58e/2959435/750e41264699/e-64-m1327-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a58e/2959435/d09b85f11687/e-64-m1327-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a58e/2959435/750e41264699/e-64-m1327-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a58e/2959435/d09b85f11687/e-64-m1327-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a58e/2959435/750e41264699/e-64-m1327-fig2.jpg

相似文献

1
catena-Poly[[bis-[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN)pyridine]cadmium(II)]-di-μ-thio-cyanato-κN:S;κS:N]: a one-dimensional coordination polymer.链状聚[[双-[2-氯-6-(1H-1,2,4-三唑-1-基-κN)吡啶]镉(II)]-二-μ-硫氰酸根-κN:S;κS:N]：一种一维配位聚合物。
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 27;64(Pt 10):m1327. doi: 10.1107/S1600536808030547.
2
catena-Poly[[bis-[2-(1H-1,2,4-triazol-1-yl-κN)pyrazine]cadmium(II)]-di-μ-thio-cyanato-κS:N;κN:S].链状聚[[双-[2-(1H-1,2,4-三唑-1-基-κN)吡嗪]镉(II)]-二-μ-硫氰酸根合-κS:N;κN:S]
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m935. doi: 10.1107/S1600536809027135.
3
Poly[di-μ-thiocyanato-κN:S;κS:N-bis-[2-(1H-1,2,3-triazol-1-yl-κN)pyra-zine]cadmium(II)].聚[二-μ-硫氰酸根合-κN:S;κS:N-双-[2-(1H-1,2,3-三唑-1-基-κN)吡嗪]镉(II)]
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 12;65(Pt 10):m1211. doi: 10.1107/S1600536809036332.
4
Di-μ-thio-cyanato-κN:S;κS:N-bis-({2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}(thio-cyanato-κN)cadmium).二-μ-硫氰酸根合-κN:S;κS:N-双-({2-吗啉代-N-[1-(2-吡啶基)亚乙基]乙胺-κN,N',N''}(硫氰酸根合-κN))镉
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m251. doi: 10.1107/S1600536811002480.
5
Crystal structure of catena-poly[[(3-tert-butyl-pyridine-κN)(4-tert-butyl-pyridine-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].链状聚[[(3-叔丁基吡啶-κN)(4-叔丁基吡啶-κN)镉]-二-μ-硫氰酸根合-κ(2)N:S;κ(2)S:N]的晶体结构
Acta Crystallogr Sect E Struct Rep Online. 2014 Nov 19;70(Pt 12):m403-4. doi: 10.1107/S1600536814024647. eCollection 2014 Dec 1.
6
catena-Poly[[(8-amino-quinoline-κN,N')cadmium]-di-μ-thio-cyanato-κN:S;κS:N-[(8-amino-quinoline-κN,N')cadmium]-di-μ-chlorido].链状聚[[(8-氨基喹啉-κN,N')镉]-二-μ-硫氰酸根合-κN:S;κS:N-[(8-氨基喹啉-κN,N')镉]-二-μ-氯合]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m3. doi: 10.1107/S1600536811051373. Epub 2011 Dec 3.
7
catena-Poly[[bis-(pyridine-κN)cadmium]-di-μ(2)-thio-cyanato-κN:S;κS:N].链状聚[[双（吡啶-κN）镉]-二-μ（2）-硫氰酸根合-κN：S；κS：N]
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m481. doi: 10.1107/S1600536811009871. Epub 2011 Mar 26.
8
Syntheses and crystal structures of bis-(4-methyl-pyridine-κ)bis-(seleno-cyanato-κ)zinc(II) and -poly[[bis-(4-methyl-pyridine-κ)cadmium(II)]-di-μ-seleno-cyanato-κ :;κ :].双（4-甲基吡啶-κ）双（硒氰酸根合-κ）锌（II）和聚[[双（4-甲基吡啶-κ）镉（II）]-二-μ-硒氰酸根合-κ:;κ:]的合成与晶体结构
Acta Crystallogr E Crystallogr Commun. 2023 Feb 7;79(Pt 3):136-141. doi: 10.1107/S2056989023000920. eCollection 2023 Feb 1.
9
catena-Poly[[(2-{[2-(dimethyl-ammonio)-eth-yl]imino-meth-yl}pyridine-κ(2)N,N')bis-(thio-cyanato-κN)manganese(II)]-μ-thio-cyanato-κ(2)N:S].链状聚[[(2-{[2-(二甲基铵基)乙基]亚氨基甲基}吡啶-κ(2)N,N')双(硫氰酸根合-κN)锰(II)]-μ-硫氰酸根合-κ(2)N:S]
Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1131. doi: 10.1107/S1600536812032874. Epub 2012 Jul 28.
10
Poly[bis(μ(3)-thio-cyanato-κN:S:S')(μ(2)-thio-cyanato-κN:S)(4'-p-tolyl-2,2':6',2''-terpyridine-κN,N',N'')cadmium(II)silver(I)].聚[双(μ(3)-硫氰酸根合-κN:S:S')(μ(2)-硫氰酸根合-κN:S)(4'-对甲苯基-2,2':6',2''-三联吡啶-κN,N',N'')镉(II)银(I)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1313-4. doi: 10.1107/S160053681003744X.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Synthesis, crystal structure, magnetic properties and theoretical studies on a one-dimensional polynuclear copper(II) complex [Cu2(mu1,3-SCN)2(mu'1,3-SCN)2(MPyO)2]n.一维多核铜（II）配合物[Cu2(μ1,3-SCN)2(μ'1,3-SCN)2(MPyO)2]n的合成、晶体结构、磁性及理论研究
Dalton Trans. 2006 Jan 14(2):376-80. doi: 10.1039/b507723k. Epub 2005 Oct 24.