链状聚[[双-[2-氯-6-(1H-1,2,4-三唑-1-基-κN)吡啶]镉(II)]-二-μ-硫氰酸根-κN:S;κS:N]：一种一维配位聚合物。
catena-Poly[[bis-[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN)pyridine]cadmium(II)]-di-μ-thio-cyanato-κN:S;κS:N]: a one-dimensional coordination polymer.
作者信息
Yang Zhong Nian, Sun Ting Ting
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 27;64(Pt 10):m1327. doi: 10.1107/S1600536808030547.
In the crystal structure of the title complex, Cd(NCS)(2)(C(7)H(5)ClN(4))(2), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octa-hedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine mol-ecule acts as a terminal ligand. The thio-cyanate ligands function as μ(1,3)-bridging units connecting adjacent Cd(II) atoms with a separation of 5.7525 (11) Å, forming a one-dimensional chain along the a axis.
在标题配合物Cd(NCS)(2)(C(7)H(5)ClN(4))(2)的晶体结构中，Cd(II)原子位于一个晶体学倒转中心上，并呈现出扭曲的八面体几何构型。2-氯-6-(1H-1,2,4-三唑-1-基)吡啶分子作为末端配体。硫氰酸根配体作为μ(1,3)-桥连单元，以5.7525 (11) Å的间距连接相邻的Cd(II)原子，沿a轴形成一维链。
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