链状聚[[双-[2-(1H-1,2,4-三唑-1-基-κN)吡嗪]镉(II)]-二-μ-硫氰酸根合-κS:N;κN:S]
catena-Poly[[bis-[2-(1H-1,2,4-triazol-1-yl-κN)pyrazine]cadmium(II)]-di-μ-thio-cyanato-κS:N;κN:S].
作者信息
Li Hong, Xie Long Miao
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m935. doi: 10.1107/S1600536809027135.
Abstract
The title compound, Cd(NCS)(2)(C(6)H(5)N(5))(2), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa-hedral geometry. The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].
摘要
标题化合物[Cd(NCS)₂(C₆H₅N₅)₂]ₙ是一种配位聚合物，镉（II）中心位于二重旋转轴上。镉（II）中心呈扭曲的八面体几何构型。硫氰酸根阴离子作为镉（II）中心之间的桥连配体，导致形成沿[001]方向延伸的链状排列。
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