Poly[bis(μ(3)-thio-cyanato-κN:S:S')(μ(2)-thio-cyanato-κN:S)(4'-p-tolyl-2,2':6',2''-terpyridine-κN,N',N'')cadmium(II)silver(I)].
作者信息
Li Yu-Yang, Wei Zhen-Hong, Ng Seik Weng
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):m1313-4. doi: 10.1107/S160053681003744X.
Abstract
The title compound, AgCd(NCS)(3)(C(22)H(17)N(3)), is a hetero-atom ribbon coordination polymer. The central Cd atom is chelated by the 4'-p-tolyl-2,2':6',2''-terpyridine ligand and is coordinated by the N atoms of three thio-cyanate ions in an octa-hedral geometry whereas the Ag atom is coordinated by the four S atoms of four thio-cyanate ions in a distorted tetra-hedral geometry. Of the three thio-cyanate ions, one functions in a μ(2)-bridging mode and two in a μ(3)-bridging mode. The ribbon coordination polymer propagates along the a-axis.
摘要
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