二水合双[3-氯-6-(3,5-二甲基-1H-吡唑-1-基)吡啶甲酸根-κO,N,N']铜(II)
Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κO,N,N']copper(II) tetra-hydrate.
作者信息
Zhao Kai, Yin Xian-Hong, Hu Fei-Long, Lin Cui-Wu, Zhang Shang-Shang, Qing Ru-Wen
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m284-5. doi: 10.1107/S1600536807068110.
In the title complex, [Cu(C(11)H(9)ClN(3)O(2))(2)]·4H(2)O, the Cu(II) atom is in a distorted octa-hedral coordination environment, coordinated by four N atoms and two O atoms from two tridentate 3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The mol-ecules are linked via inter-molecular O-H⋯O hydrogen bonds involving water mol-ecules to form extended chains along [010], and there are short Cl⋯Cl contacts [3.153 (4) Å].
在标题配合物[Cu(C₁₁H₉ClN₃O₂)₂]·4H₂O中，Cu(II)原子处于扭曲的八面体配位环境中，由来自两个三齿3-氯-6-(3,5-二甲基-1H-吡唑-1-基)吡啶甲酸酯配体的四个N原子和两个O原子配位。分子通过涉及水分子的分子间O—H⋯O氢键相连，沿[010]形成延伸链，并且存在短的Cl⋯Cl接触[3.153(4) Å]。
Zotero 插件