• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双{μ-2,2'-[1,1'-(乙烷-1,2-二腈基二亚乙基)二亚苯基]二酚根合-κO,N,N',O':O}双[氯化锰(III)]

Bis{μ-2,2'-[1,1'-(ethane-1,2-diyldinitrilo)diethyl-idyne]diphenolato-κO,N,N',O':O}bis-[chloridomanganese(III)].

作者信息

Thampidas V S, Radhakrishnan T, Pike Robert D

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):m307. doi: 10.1107/S1600536808000226.

DOI:10.1107/S1600536808000226
PMID:21201280
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960426/
Abstract

The title compound, [Mn(2)(C(18)H(18)N(2)O(2))(2)Cl(2)], was synthesized by the reaction between manganese(II) o-chloro-benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxy-acetophenone. The centrosymmetric dimer contains two Jahn-Teller-distorted mangan-ese(III) ions, each in an octa-hedral geometry, connected through two phen-oxy bridges from two ligands.

摘要

标题化合物[Mn₂(C₁₈H₁₈N₂O₂)₂Cl₂]是通过邻氯苯甲酸锰(II)与乙二胺和邻羟基苯乙酮缩合原位生成的席夫碱反应合成的。中心对称二聚体包含两个具有 Jahn-Teller 畸变的锰(III)离子，每个离子呈八面体几何构型，通过来自两个配体的两个苯氧基桥相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b284/2960426/d834981bafdf/e-64-0m307-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b284/2960426/d834981bafdf/e-64-0m307-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b284/2960426/d834981bafdf/e-64-0m307-fig1.jpg

相似文献

1
Bis{μ-2,2'-[1,1'-(ethane-1,2-diyldinitrilo)diethyl-idyne]diphenolato-κO,N,N',O':O}bis-[chloridomanganese(III)].双{μ-2,2'-[1,1'-(乙烷-1,2-二腈基二亚乙基)二亚苯基]二酚根合-κO,N,N',O':O}双[氯化锰(III)]
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):m307. doi: 10.1107/S1600536808000226.
2
Bis{μ-2,2'-[1,1'-(ethane-1,2-diyldinitrilo)diethyl-idyne]diphenolato}bis-[(benzoato-κO)manganese(III)] dihydrate.二水合双{μ-2,2'-[1,1'-(乙烷-1,2-二腈基)二亚乙基]二酚根合}双[(苯甲酸根-κO)锰(III)]
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 12;64(Pt 1):m150-1. doi: 10.1107/S160053680706446X.
3
Bis{μ-4,4'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}bis-({4,4'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenol}manganese(III)) bis-(hexa-fluorido-phosphate).双{μ-4,4'-二甲氧基-2,2'-[丙烷-1,2-二亚基双(腈基亚甲基)]二酚盐}双({4,4'-二甲氧基-2,2'-[丙烷-1,2-二亚基双(腈基亚甲基)]二酚}锰(III))双(六氟磷酸根)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 29;65(Pt 8):m1004-5. doi: 10.1107/S1600536809028591.
4
Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}(4-hydroxy-benzoato)manganese(III).水合-{6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合}(4-羟基苯甲酸根)锰(III)
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 22;65(Pt 9):m1110-1. doi: 10.1107/S1600536809032553.
5
catena-Poly[[[{5,5'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}manganese(III)]-μ-acetato] methanol monosolvate].链状聚[[[{5,5'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨甲基亚基)]二酚根合}锰(III)]-μ-乙酸根]甲醇单溶剂合物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 9;66(Pt 11):m1384-5. doi: 10.1107/S160053681003984X.
6
Diaqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate.高氯酸二水合-{6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-κO,N,N',O'}锰(III) 18-冠-6半溶剂合物一水合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m153. doi: 10.1107/S1600536808044176.
7
The cocrystal aqua-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}-manganese(III)-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}(methanol-κO)manganese(III) (1/1).氯代水合{6,6'-二叔丁基-2,2'-[1,2-亚苯基双(次氮基甲基亚基)]二酚根合-κO,N,N',O'}-锰(III)-氯代{6,6'-二叔丁基-2,2'-[1,2-亚苯基双(次氮基甲基亚基)]二酚根合-κO,N,N',O'}(甲醇-κO)锰(III) (1/1)
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 4;64(Pt 5):m626-7. doi: 10.1107/S1600536808006818.
8
Bis(μ-2-phen-oxy-propionato-κO:O')bis-[(1,10-phenanthroline-κN,N')bis-(2-phen-oxy-propionato-κO,O')samarium(III)].双（μ-2-苯氧基丙酸根-κO:O'）双[（1,10-菲咯啉-κN,N'）双（2-苯氧基丙酸根-κO,O'）]钐（III）
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1319. doi: 10.1107/S1600536811034829. Epub 2011 Aug 31.
9
Bis(μ(2)-2-phen-oxy-propionato-κO:O')bis-[(1,10-phenanthroline-κN,N')bis-(2-phen-oxy-propionato-κO,O')ytterbium(III)].双（μ(2)-2-苯氧基丙酸根-κO:O'）双[（1,10-菲咯啉-κN,N'）双（2-苯氧基丙酸根-κO,O'）镱（III）]
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1361. doi: 10.1107/S1600536811036105. Epub 2011 Sep 14.
10
Diaqua-1κO,3κO-di-μ-cyanido-1:2κN:C;2:3κC:N-dicyanido-2κN-bis-{4,4'-dibromo-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}-1κO,N,N',O';3κO,N,N',O'-1,3-dimanganese(III)-2-nickel(II).二水合-1κO,3κO-二-μ-氰基-1:2κN:C;2:3κC:N-二氰基-2κN-双-{4,4'-二溴-2,2'-[丙烷-1,2-二亚基双(亚氨基亚甲基)]二酚根合}-1κO,N,N',O';3κO,N,N',O'-1,3-二锰(III)-2-镍(II)
Acta Crystallogr Sect E Struct Rep Online. 2008 May 7;64(Pt 6):m783. doi: 10.1107/S1600536808012749.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Preparation of highly efficient manganese catalase mimics.高效锰过氧化氢酶模拟物的制备。
Inorg Chem. 2002 Oct 21;41(21):5544-54. doi: 10.1021/ic025897a.