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高氯酸二水合-{6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(腈基亚甲基)]二酚根合-κO,N,N',O'}锰(III) 18-冠-6半溶剂合物一水合物

Diaqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) perchlorate 18-crown-6 hemisolvate monohydrate.

作者信息

Li Zhan-Xian, Li Xia, Zhang Li-Feng, Yu Ming-Ming

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m153. doi: 10.1107/S1600536808044176.

DOI:10.1107/S1600536808044176
PMID:21581765
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968196/
Abstract

In the cation of the title compound, [Mn(C(18)H(18)N(2)O(4))(H(2)O)(2)]ClO(4)·0.5C(12)H(24)O(6)·H(2)O, the Mn(III) ion is coordinated by two water O atoms, and two O atoms and two N atoms from the tetradentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]di-phenolate ligand, completing a distorted octa-hedral geometry. One O atom of the 18-crown-6-ether is disordered over two positions with occupancies of 0.70 (2) and 0.30 (2).

摘要

在标题化合物[Mn(C₁₈H₁₈N₂O₄)(H₂O)₂]ClO₄·0.5C₁₂H₂₄O₆·H₂O的阳离子中，Mn(III)离子由两个水分子的O原子、以及来自四齿配体6,6'-二甲氧基-2,2'-[乙烷-1,2-二基双(亚氨甲基亚基)]二酚盐的两个O原子和两个N原子配位，形成一个扭曲的八面体几何构型。18-冠-6-醚的一个O原子在两个位置上无序，占有率分别为0.70 (2)和0.30 (2)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/2968196/34c008ca6bda/e-65-0m153-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/2968196/34c008ca6bda/e-65-0m153-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af1b/2968196/34c008ca6bda/e-65-0m153-fig1.jpg

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引用本文的文献

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