{2-[(S)-({2-[(S)-1-苄基-吡咯烷-2-甲酰胺基]苯基}(苯基)亚甲基)氨基]-4-羟基丁酸根-κN,N',N'',O}镍(II)
{2-[(S)-({2-[(S)-1-Benzyl-pyrrolidine-2-carboxamido]phen-yl}(phen-yl)methyl-ene)amino]-4-hydroxy-butanoato-κN,N',N'',O}nickel(II).
作者信息
Popkov Alexander, Nádvorník Milan, Kožíšek Jozef
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 16;64(Pt 2):m364-5. doi: 10.1107/S1600536808000949.
Abstract
The central Ni atom of the title compound, [Ni(C(29)H(29)N(3)O(4))], is coordinated by three N atoms [Ni-N = 1.955 (2), 1.844 (2) and 1.872 (2) Å] and by one O atom [Ni-O = 1.862 (2) Å] in a pseudo-square-planar geometry. The conformation of the hydroxy-butanoate side chain is controlled by a strong intra-molecular hydrogen bond (H⋯O = 1.84 Å).
摘要
标题化合物[Ni(C₂₉H₂₉N₃O₄)]的中心镍原子由三个氮原子[Ni-N = 1.955 (2)、1.844 (2)和1.872 (2) Å]和一个氧原子[Ni-O = 1.862 (2) Å]配位，呈假平面正方形几何构型。羟基丁酸酯侧链的构象受一个强分子内氢键（H⋯O = 1.84 Å）控制。
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