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[2-((R)-{2-[(S)-1-Benzylpyrrolidin-2-ylcarbonylazanidyl]-phen-yl}(phen-yl)methyl-idene-amino)-4-hy-droxy-butano-ato-κN,N',N'',O]nickel(II) toluene disolvate.

作者信息

Padělková Zdeňka, Popkov Alexander, Nádvorník Milan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1258-9. doi: 10.1107/S1600536811031059. Epub 2011 Aug 17.

Abstract

The central Ni atom in the title compound, [Ni(C(29)H(29)N(3)O(4))]·2C(7)H(8), is coordinated in a distorted square-planar environment by three N atoms [Ni-N = 1.942 (3), 1.843 (3) and 1.853 (3) Å] and one O atom [1.868 (3) Å] of the tetradentate ligand. The conformation of the hy-droxy-butano-ate side chain is controlled by an inter-molecular hydrogen bond.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6ed/3200655/f7e2c0ed1ed5/e-67-m1258-fig1.jpg

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本文引用的文献

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{2-[(S)-({2-[(S)-1-Benzyl-pyrrolidine-2-carboxamido]phen-yl}(phen-yl)methyl-ene)amino]-4-hydroxy-butanoato-κN,N',N'',O}nickel(II).
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Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
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