Huang Jin-Feng, Dai Yu-Mei, Lin Jian-Rong, Lin Hui, Tang En
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 23;64(Pt 2):m386. doi: 10.1107/S1600536808001621.
The title compound, Zn(C(8)H(4)O(4))(C(13)H(14)N(2)), was obtained by the hydro-thermal reaction of Zn(OAc)(2)·H(2)O with 1,3-di-4-pyridylpropane (bpp) and isophthalic acid (H(2)ip). The Zn(II) ion is coordinated by two bpp and two ip ligands in a distorted tetra-hedral environment. Each ligand coordinates in a bridging mode to connect Zn(II) ions into a three-dimensional diamondoid-type structure.
标题化合物[Zn(C₈H₄O₄)(C₁₃H₁₄N₂)]ₙ是通过乙酸锌一水合物(Zn(OAc)₂·H₂O)与1,3-二(4-吡啶基)丙烷(bpp)和间苯二甲酸(H₂ip)的水热反应得到的。Zn(II)离子在扭曲的四面体环境中由两个bpp和两个间苯二甲酸配体配位。每个配体以桥连模式配位,将Zn(II)离子连接成三维类金刚石型结构。