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聚[（μ(6)-苯-1,2,4,5-四羧酸根）双（1,10-菲咯啉-κN,N'）二锰（II）]

Poly[(μ(6)-benzene-1,2,4,5-tetra-carboxyl-ato)bis-(1,10-phenanthroline-κN,N')dimanganese(II)].

作者信息

Jiang Xin-Dong, Li Xiu-Bing, Sun Bai-Wang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 13;64(Pt 7):m922-3. doi: 10.1107/S1600536808016723.

DOI:10.1107/S1600536808016723
PMID:21202779
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961681/
Abstract

The title polymeric compound, Mn(2)(C(10)H(2)O(8))(C(12)H(8)N(2))(2), was obtained by the reaction of manganese(II) chloride tetra-hydrate with benzene-1,2,4,5-tetra-carboxylic acid (H(4)bta) in aqueous solution. Each Mn(2+) ion is coordinated in a distorted octa-hedral geometry by two N atoms from one 1,10-phenanthroline ligand and four O atoms [Mn-O = 2.116 (2)-2.237 (2) Å] from three bta(4-) ligands, which also act as bridging groups between the Mn(2+) ions.

摘要

聚合物化合物[Mn₂(C₁₀H₂O₈)(C₁₂H₈N₂)₂]ₙ是通过四水合氯化锰与苯-1,2,4,5-四羧酸（H₄bta）在水溶液中反应得到的。每个Mn²⁺离子由来自一个1,10-菲咯啉配体的两个N原子和来自三个bta⁴⁻配体的四个O原子[Mn - O = 2.116 (2)-2.237 (2) Å]以扭曲的八面体几何构型配位，这些bta⁴⁻配体也作为Mn²⁺离子之间的桥连基团。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/933b/2961681/0e389668d1a9/e-64-0m922-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/933b/2961681/86bdae3a1d57/e-64-0m922-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/933b/2961681/0cd2033407d3/e-64-0m922-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/933b/2961681/0e389668d1a9/e-64-0m922-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/933b/2961681/86bdae3a1d57/e-64-0m922-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/933b/2961681/0cd2033407d3/e-64-0m922-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/933b/2961681/0e389668d1a9/e-64-0m922-fig3.jpg

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