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{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二亚基双(次氮基甲基亚基)]二酚根合}二甲醇三硝酸镍(II)镧(III)甲醇溶剂合物

{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}dimethano-ltrinitratonickel(II)lanthanum(III) methanol disolvate.

作者信息

Liu Fei

机构信息

College of Chemical Engineering and Materials, Eastern Liaoning University, 325 Wenhua Road, Yuanbao District, Dandong City, Liaoning Province, 118003, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):m1207. doi: 10.1107/S1600536808026986.

Abstract

In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa-hedral geometry. The La(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-anti-prismatic environment. In the crystal structure, inter-molecular O-H-O hydrogen bonds connect complex mol-ecules and methanol solvent mol-ecules, forming a two-dimensional network.

摘要

在双核配合物[NiLa(C₁₉H₂₀N₂O₄)(NO₃)₃(CH₃OH)₂]·2CH₃OH中,Ni(II)离子由席夫碱配体的两个O原子和两个N原子以及两个甲醇配体的两个O原子配位,形成略微扭曲的八面体几何构型。La(III)离子由来自三个螯合硝酸根配体的六个O原子和来自席夫碱配体的四个O原子配位,形成扭曲的双帽四方反棱柱环境。在晶体结构中,分子间的O-H-O氢键连接配合物分子和甲醇溶剂分子,形成二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0bcf/2960610/4f923001b058/e-64-m1207-fig1.jpg

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