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{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二亚基双(腈基亚甲基)]二苯酚根合 - 1κO,O,O,O:2κO,N,N',O}(甲醇 - 1κO)(高氯酸根 - 1κO)铜(II)钠(I)

{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I).

作者信息

Xiao Hui-Quan, Zhang Hua

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m445. doi: 10.1107/S1600536809010356.

DOI:10.1107/S1600536809010356
PMID:21582382
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969023/
Abstract

The mol-ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar with mean deviation of 5.2 (8)°. The coordination environment of the Cu(II) ion is distorted square-planar and it is N(2)O(2)-chelated by the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Na atom is chelated by the four O atoms of the Schiff base ligand, and coordinated by a methanol mol-ecule and a perchlorate anion. The six-coordinate Na atom adopts a distorted octa-hedral coordination geometry. The O atoms of the perchlorate anion are disordered over two sites with site-occupancy factors of 0.697 (5) and 0.303 (5). O-H⋯O hydrogen bonding occurs.

摘要

标题化合物[CuNa(C₁₈H₁₈N₂O₄)(ClO₄)(CH₃OH)]的分子几乎呈平面状，平均偏差为5.2 (8)°。Cu(II)离子的配位环境为扭曲的平面正方形，它被6,6'-二甲氧基-2,2'-[乙烷-1,2-二亚基双(次氮基甲基亚基)]二酚盐席夫碱配体以N₂O₂方式螯合。Na原子被席夫碱配体的四个O原子螯合，并由一个甲醇分子和一个高氯酸根阴离子配位。六配位的Na原子采用扭曲的八面体配位几何构型。高氯酸根阴离子的O原子在两个位置上无序，占位因子分别为0.697 (5)和0.303 (5)。存在O—H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e7f/2969023/555c47b5a747/e-65-0m445-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e7f/2969023/555c47b5a747/e-65-0m445-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e7f/2969023/555c47b5a747/e-65-0m445-fig1.jpg

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本文引用的文献

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