• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2-羟基-5-硝基苯甲醛2,4-二硝基苯腙

2-Hydr-oxy-5-nitro-benzaldehyde 2,4-dinitro-phenyl-hydrazone.

作者信息

A Tameem Abdassalam, Saad Bahruddin, Salhin Abdussalam M, Jebas Samuel Robinson, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 7;64(Pt 4):o679-80. doi: 10.1107/S1600536808005825.

DOI:10.1107/S1600536808005825
PMID:21202072
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961021/
Abstract

In the title compound, C(13)H(9)N(5)O(7), one of the nitro groups is twisted away from the attached benzene ring by 16.21 (8)°. The dihedral angle between the two benzene rings is 4.63 (1)°. The mol-ecular structure is stabilized by intra-molecular N-H⋯O and O-H⋯N hydrogen bonds which generate an S(6) ring motif. The mol-ecules pack as layers parallel to the ab plane; mol-ecules of adjacent layers are linked into chains along the [101] direction through N-H⋯O hydrogen bonds.

摘要

在标题化合物C₁₃H₉N₅O₇中，其中一个硝基与相连的苯环扭转了16.21 (8)°。两个苯环之间的二面角为4.63 (1)°。分子结构通过分子内N-H⋯O和O-H⋯N氢键得以稳定，这些氢键形成了一个S(6)环模式。分子堆积成与ab平面平行的层；相邻层的分子通过N-H⋯O氢键沿[101]方向连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/113f/2961021/7531f09f9d77/e-64-0o679-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/113f/2961021/fb9b0c94933e/e-64-0o679-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/113f/2961021/7531f09f9d77/e-64-0o679-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/113f/2961021/fb9b0c94933e/e-64-0o679-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/113f/2961021/7531f09f9d77/e-64-0o679-fig2.jpg

相似文献

1
2-Hydr-oxy-5-nitro-benzaldehyde 2,4-dinitro-phenyl-hydrazone.2-羟基-5-硝基苯甲醛2,4-二硝基苯腙
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 7;64(Pt 4):o679-80. doi: 10.1107/S1600536808005825.
2
2-Methoxy-benzaldehyde 2,4-dinitro-phenyl-hydrazone.2-甲氧基苯甲醛2,4-二硝基苯腙
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):o246-7. doi: 10.1107/S1600536809000038.
3
2-Hydr-oxy-N'-(2-hydr-oxy-4-methoxy-benzyl-idene)-3-methyl-benzohydrazide monohydrate.2-羟基-N'-(2-羟基-4-甲氧基亚苄基)-3-甲基苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 May 15;66(Pt 6):o1340. doi: 10.1107/S1600536810016855.
4
4-Hydr-oxy-N'-(2-hydr-oxy-3-methoxy-benzyl-idene)benzohydrazide mono-hydrate.4-羟基-N'-(2-羟基-3-甲氧基亚苄基)苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 27;64(Pt 10):o2032. doi: 10.1107/S1600536808030894.
5
(E)-3-Bromo-N'-(4-hydr-oxy-3-nitro-benzyl-idene)benzohydrazide.
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 1;65(Pt 8):o1725. doi: 10.1107/S1600536809024131.
6
4-[(5-Hydr-oxy-3-methyl-1-phenyl-1H-pyrazol-4-yl)phenyl-meth-yl]-5-methyl-2-phenyl-1H-pyrazol-3(2H)-one ethanol hemisolvate.4-[(5-羟基-3-甲基-1-苯基-1H-吡唑-4-基)苯甲基]-5-甲基-2-苯基-1H-吡唑-3(2H)-酮乙醇半溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):o66-7. doi: 10.1107/S1600536808039081.
7
(E)-2,4-Dihydr-oxy-N'-(2-hydr-oxy-3-meth-oxy-5-nitro-benzyl-idene)benzohydrazide dihydrate.（E）-2,4-二羟基-N'-（2-羟基-3-甲氧基-5-硝基亚苄基）苯甲酰肼二水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14;66(Pt 5):o1085-6. doi: 10.1107/S1600536810013000.
8
Crystal structure of ()-4-hy-droxy-'-(3-meth-oxy-benzyl-idene)benzohydrazide.（）-4-羟基-'-（3-甲氧基-亚苄基）苯甲酰肼的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Aug 26;72(Pt 9):1339-1342. doi: 10.1107/S2056989016013268. eCollection 2016 Sep 1.
9
2-Hydr-oxy-N'-(2-hydr-oxy-3-meth-oxy-5-nitro-benzyl-idene)-3-methyl-benzo-hydrazide.
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14;66(Pt 5):o1084. doi: 10.1107/S1600536810012912.
10
(E)-1-(3-Methoxy-phen-yl)ethanone 4-nitro-phenyl-hydrazone.（E）-1-（3-甲氧基苯基）乙酮4-硝基苯腙
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):o1341. doi: 10.1107/S1600536808018618.

引用本文的文献

1
(E)-4-Hy-droxy-N'-(2-hy-droxy-4-meth-oxy-benzyl-idene)benzohydrazide.（E）-4-羟基-N'-（2-羟基-4-甲氧基苄叉基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):o2279. doi: 10.1107/S1600536812027201. Epub 2012 Jun 30.
2
1-(2,3-Dimeth-oxy-benzyl-idene)-2-(2,4-dinitro-phen-yl)hydrazine.1-（2,3-二甲氧基-亚苄基）-2-（2,4-二硝基-苯基）肼
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1169. doi: 10.1107/S1600536811013894. Epub 2011 Apr 16.
3
(E)-4-Hy-droxy-N'-(4-hy-droxy-3-meth-oxy-benzyl-idene)benzohydrazide.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
N-2-hydroxy-4-methoxyacetophenone-N'-4-nitrobenzoyl hydrazine: synthesis and structural characterization.N-2-羟基-4-甲氧基苯乙酮-N'-4-硝基苯甲酰肼：合成与结构表征
Spectrochim Acta A Mol Biomol Spectrosc. 2007 Apr;66(4-5):898-903. doi: 10.1016/j.saa.2006.05.006. Epub 2006 May 10.
3
Isomerization of aldehyde-2,4-dinitrophenylhydrazone derivatives and validation of high-performance liquid chromatographic analysis.
（E）-4-羟基-N'-（4-羟基-3-甲氧基苄叉基）苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 13;66(Pt 12):o3126-7. doi: 10.1107/S1600536810045162.
4
1-[(Bromo-meth-yl)(phen-yl)meth-ylene]-2-(2,4-dinitro-phen-yl)hydrazine.1-[(溴甲基)(苯基)亚甲基]-2-(2,4-二硝基苯基)肼
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):o1221-2. doi: 10.1107/S1600536809016225.
5
Ethyl 4-(1,3-dioxo-2,3-dihydro-1H-benzo[de]isoquinolin-2-yl)benzoate.
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):o98-9. doi: 10.1107/S160053681005049X.
醛-2,4-二硝基苯腙衍生物的异构化及高效液相色谱分析的验证
J Chromatogr A. 2003 May 9;996(1-2):95-102. doi: 10.1016/s0021-9673(03)00542-9.
4
Characterization of a chemical artifact in the liquid chromatographic determination of 3-butyn-2-one using the 2,4-dinitrophenylhydrazine method.
J Chromatogr A. 2000 Jul 21;886(1-2):303-7. doi: 10.1016/s0021-9673(00)00484-2.
5
High-performance liquid chromatography of methanol released from pectins after its oxidation to formaldehyde and condensation with 2,4-dinitrophenylhydrazine.果胶氧化成甲醛并与2,4-二硝基苯肼缩合后释放出的甲醇的高效液相色谱法。
J Chromatogr A. 1999 Nov 26;863(2):227-33. doi: 10.1016/s0021-9673(99)00985-1.
6
High-performance liquid chromatographic peak identification of 2,4-dinitrophenylhydrazine derivatives of lipid peroxidation aldehydes by photodiode array detection.通过光电二极管阵列检测对脂质过氧化醛的2,4-二硝基苯肼衍生物进行高效液相色谱峰鉴定。
J Chromatogr A. 1998 Mar 6;798(1-2):117-23. doi: 10.1016/s0021-9673(97)01161-8.