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4-[(E)-(5-氯-2-羟基-亚苄基)氨基]苯磺酰胺

4-[(E)-(5-Chloro-2-hydroxy-benzyl-idene)amino]benzene-sulfonamide.

作者信息

Chohan Zahid H, Shad Hazoor A, Tahir M Nawaz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):o57. doi: 10.1107/S1600536808040853.

DOI:10.1107/S1600536808040853
PMID:21581698
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2967971/
Abstract

In the mol-ecule of title compound, C(13)H(11)ClN(2)O(3)S, the aromatic rings are oriented at a dihedral angle of 12.27 (3)°. An intra-molecular O-H⋯N hydrogen bond results in the formation of a planar (mean deviation 0.0083 Å) six-membered ring, which is nearly coplanar with the adjacent ring at a dihedral angle of 2.36 (13)°. In the sulfonamide group, the S atom is 0.457 (3) Å from the plane through the O and N atoms. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules.

摘要

在标题化合物C(13)H(11)ClN(2)O(3)S的分子中，芳环的二面角为12.27 (3)°。分子内的O-H⋯N氢键导致形成一个平面（平均偏差0.0083 Å）六元环，该六元环与相邻环几乎共面，二面角为2.36 (13)°。在磺酰胺基团中，S原子距通过O和N原子的平面0.457 (3) Å。在晶体结构中，分子间的N-H⋯O氢键连接这些分子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5bc/2967971/565d1d6d2aa8/e-65-00o57-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5bc/2967971/1f51d7279089/e-65-00o57-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5bc/2967971/565d1d6d2aa8/e-65-00o57-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5bc/2967971/1f51d7279089/e-65-00o57-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d5bc/2967971/565d1d6d2aa8/e-65-00o57-fig2.jpg

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