双[4-(4-甲氧基-苯基)-4H-1,2,4-三唑-κN]双(硫氰酸根合-κN)锌(II)
Bis[4-(4-methoxy-phen-yl)-4H-1,2,4-triazole-κN]bis-(thio-cyanato-κN)zinc(II).
作者信息
Zuo Ya
机构信息
College of Science, Inner Mongolia Agricultural University, Inner Mongolia 010018, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 2;64(Pt 5):m609. doi: 10.1107/S1600536808008325.
Abstract
In the title complex, [Zn(NCS)(2)(C(9)H(9)N(3)O)(2)], the Zn(II) ion is coordinated by two N atoms from the NCS(-) anions and two N atoms from two 4-(4-methoxy-phen-yl)-4H-1,2,4-triazole ligands in a slightly distorted tetra-hedral geometry. Three inter-molecular weak hydrogen-bonding contacts of the types C-H⋯N, C-H⋯S and C-H⋯O are observed in the crystal structure.
摘要
在标题配合物[Zn(NCS)₂(C₉H₉N₃O)₂]中，Zn(II)离子由两个NCS⁻阴离子中的N原子和两个4-(4-甲氧基苯基)-4H-1,2,4-三唑配体中的N原子配位，形成略微扭曲的四面体几何构型。在晶体结构中观察到三种类型的分子间弱氢键接触，即C-H⋯N、C-H⋯S和C-H⋯O。
Zotero 插件