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cis-Dichloridobis[2-(hydroxy-meth-yl)tetra-hydro-furan-κO,O']manganese(II).

作者信息

Jerzykiewcz Lucjan B, Utko Józef, Sobota Piotr

机构信息

Faculty of Chemistry, University of Wrocław, 14. F. Joliot Curie, 50-383 Wrocław, Poland.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 10;64(Pt 5):m657-8. doi: 10.1107/S1600536808009549.

Abstract

The structure of the title compound, [MnCl(2)(C(5)H(10)O(2))(2)], was solved from low-temperature data collected at 100 (2) K. The asymmetric unit contains one half-mol-ecule with the Mn(II) ion located on a twofold axis. A distorted octa-hedral environment around the Mn atom is formed by two ether and two hydroxyl O atoms of two 2-(hydroxy-methyl)tetra-hydro-furan ligands, and by two chloride ions. The chelating tetra-hydro-furan ligands, which form five-membered rings, are cis oriented. The crystal structure is stabilized by hydrogen bonding between the coordinated OH groups and the chloride ions.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0542/2961271/4de7ebf15248/e-64-0m657-fig1.jpg

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