二羰基二氯双（三甲基膦）铁（II）-羰基二氯三（三甲基膦）铁（II）-四氢呋喃（1/1/2）
Dicarbonyl-dichloridobis(trimethyl-phosphane)iron(II)-carbonyl-dichlorido-tris(trimethyl-phosphane)iron(II)-tetra-hydro-furan (1/1/2).
作者信息
Rath Nigam P, Stouffer Meghan, Janssen Matthew K, Bleeke John R
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m462. doi: 10.1107/S1600536811009305. Epub 2011 Mar 19.
The asymmetric unit of the title crystal, [FeCl(2)(C(3)H(9)P)(3)(CO)]·[FeCl(2)(C(3)H(9)P)(2)(CO)(2)]·2C(4)H(8)O, contains half mol-ecules of the two closely related Fe(II) complexes lying on mirror planes and a tetra-hydro-furan solvent mol-ecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both Fe(II) complex mol-ecules, a distorted octa-hedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H⋯O inter-actions are observed in the crystal structure.
标题晶体[FeCl₂(C₃H₉P)₃(CO)]·[FeCl₂(C₃H₉P)₂(CO)₂]·2C₄H₈O的不对称单元包含位于镜面上的两个密切相关的Fe(II)配合物的半分子以及一个四氢呋喃溶剂分子，其中一个C原子在两组位置上无序，占位因子分别为0.633 (9)和0.367 (9)。在两个Fe(II)配合物分子中，Fe原子周围均观察到扭曲的八面体配位几何构型。晶体结构中观察到弱的分子间C—H⋯O相互作用。
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