Zukerman-Schpector Julio, Olivato Paulo R, Cerqueira Carlos R, Vinhato Elisângela, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 16;64(Pt 5):o835-6. doi: 10.1107/S1600536808009288.
The piperidone ring in the title compound, C(12)H(15)NO(3)S, has a slightly distorted half-chair conformation with the methyl, carbonyl and phenyl-sulfonyl ring substituents occupying equatorial, equatorial and axial positions, respectively. Mol-ecules are connected into centrosymmetric dimers via C-H⋯O inter-actions and these associate into layers via C-H⋯O-S contacts. Further C-H⋯O inter-actions involving both the carbonyl and sulfonyl O atoms consolidate the crystal packing by providing connections between the layers.
标题化合物C(12)H(15)NO(3)S中的哌啶酮环具有轻微扭曲的半椅构象,其中甲基、羰基和苯磺酰基环取代基分别占据赤道、赤道和轴向位置。分子通过C-H⋯O相互作用连接成中心对称二聚体,并通过C-H⋯O-S接触缔合形成层。涉及羰基和磺酰基O原子的进一步C-H⋯O相互作用通过在层之间提供连接来巩固晶体堆积。