Zukerman-Schpector Julio, De Simone Carlos A, Olivato Paulo R, Cerqueira Carlos R, Santos Jean M M, Tiekink Edward R T
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 30;66(Pt 7):o1863. doi: 10.1107/S1600536810024347.
The piperidone ring in the title compound, C(18)H(17)Cl(2)NOS(2), has a distorted half-chair conformation. The S-bound benzene rings are approximately perpendicular to and splayed out of the mean plane through the piperidone ring [dihedral angles = 71.86 (13) and 46.94 (11)°]. In the crystal, C-H⋯O inter-actions link the mol-ecules into [010] supra-molecular chains with a helical topology. C-H⋯Cl and C-H⋯π inter-actions are also present.
标题化合物C(18)H(17)Cl(2)NOS(2)中的哌啶酮环具有扭曲的半椅构象。与硫相连的苯环大致垂直于哌啶酮环的平均平面并向该平面外展开[二面角 = 71.86 (13)和46.94 (11)°]。在晶体中，C—H⋯O相互作用将分子连接成具有螺旋拓扑结构的[010]超分子链。还存在C—H⋯Cl和C—H⋯π相互作用。
