{2,2'-[亚乙基双（亚氨甲基亚基）]二酚根合-κO,N,N',O'}氧化钒(IV)
{2,2'-[Ethyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}oxido-vanadium(IV).
作者信息
Wang Cheng, Yuan Ji-Hong, Xie Gang, Yu Ming-Juan, Li Jing
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 May 7;64(Pt 6):m775-6. doi: 10.1107/S1600536808010611.
Abstract
The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N'-bis-(salicyl-idene)ethyl-enediamine under hydro-thermal conditions. The asymmetric unit contains two mol-ecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure.
摘要
标题化合物[V(C₁₆H₁₄N₂O₂)O]是通过硫酸氧钒(IV)与N,N'-双(水杨醛亚基)乙二胺在水热条件下反应合成的。不对称单元包含两个分子。每个V(IV)原子由来自配体的两个N原子和两个O原子在基面以方锥几何构型配位，顶端位置由一个氧化物O原子配位。弱的C—H⋯O氢键导致三维超分子结构。
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