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{2,2'-[亚乙基双（亚氨甲基亚基）]二酚根合-κO,N,N',O'}氧化钒(IV)

{2,2'-[Ethyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}oxido-vanadium(IV).

作者信息

Wang Cheng, Yuan Ji-Hong, Xie Gang, Yu Ming-Juan, Li Jing

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 May 7;64(Pt 6):m775-6. doi: 10.1107/S1600536808010611.

DOI:10.1107/S1600536808010611
PMID:21202467
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961374/
Abstract

The title compound, [V(C(16)H(14)N(2)O(2))O], was synthesized by the reaction of vanadyl(IV) sulfate and N,N'-bis-(salicyl-idene)ethyl-enediamine under hydro-thermal conditions. The asymmetric unit contains two mol-ecules. Each V(IV) atom is coordinated in a square-pyramidal geometry by two N atoms and two O atoms from a ligand in the basal plane and by an oxide O atom in the apical position. Weak C-H⋯O hydrogen bonds lead to a three-dimensional supra-molecular structure.

摘要

标题化合物[V(C₁₆H₁₄N₂O₂)O]是通过硫酸氧钒(IV)与N,N'-双(水杨醛亚基)乙二胺在水热条件下反应合成的。不对称单元包含两个分子。每个V(IV)原子由来自配体的两个N原子和两个O原子在基面以方锥几何构型配位，顶端位置由一个氧化物O原子配位。弱的C—H⋯O氢键导致三维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b434/2961374/dd2b7b18def2/e-64-0m775-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b434/2961374/3124f52fca66/e-64-0m775-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b434/2961374/dd2b7b18def2/e-64-0m775-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b434/2961374/3124f52fca66/e-64-0m775-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b434/2961374/dd2b7b18def2/e-64-0m775-fig2.jpg

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引用本文的文献

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Oxidation Kinetics of the Potent Insulin Mimetic Agent Bis(maltolato)oxovanadium(IV) (BMOV) in Water and in Methanol.强效胰岛素模拟剂双（麦芽醇基）氧钒（IV）（BMOV）在水和甲醇中的氧化动力学
Inorg Chem. 1996 Mar 13;35(6):1667-1673. doi: 10.1021/ic951452t.
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