双（2-苯甲酰胺基-苯并咪唑根合-κN，O）（N，N-二甲基甲酰胺-κO）铜（II）
Bis(2-benzamido-benzimidazolato-κN,O)(N,N-dimethyl-formamide-κO)copper(II).
作者信息
Thiam Elhadj Ibrahima, Tamboura Farba, Gaye Mohamed, Sall Abdou Salam, Barry Aliou Hamady
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 7;64(Pt 7):m876. doi: 10.1107/S1600536808016383.
In the title compound, [Cu(C(14)H(10)N(3)O)(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated by two N,O-bidentate 2-benzamido-benzimidazolate anions and one O-coordinated dimethyl-formamide (DMF) mol-ecule, resulting in a distorted square-based pyramidal CuN(2)O(3) geometry for the metal atom, with the DMF O atom at the apical site. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds result in chains of mol-ecules propagating along [100].
在标题化合物[Cu(C₁₄H₁₀N₃O)₂(C₃H₇NO)]中，Cu(II)原子由两个N,O-双齿的2-苯甲酰胺基苯并咪唑阴离子和一个O-配位的二甲基甲酰胺（DMF）分子五配位，金属原子形成扭曲的四方锥CuN₂O₃几何构型，DMF的O原子位于顶端位置。在晶体结构中，分子间的N-H⋯N氢键导致分子链沿[100]方向延伸。
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