{2-[6-(1H-苯并咪唑-2-基-κN)-2-吡啶基-κN]苯并咪唑根-κN}(二氰胺根-κN)(甲醇-κO)铜(II)
{2-[6-(1H-Benzimidazol-2-yl-κN)-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II).
作者信息
Hu Jingchun, Zhang Jinfang, Zhang Weiming, Zhang Chi
机构信息
Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 11;67(Pt 1):m61. doi: 10.1107/S1600536810050178.
In the title compound, [Cu(C(19)H(12)N(5))(C(2)N(3))(CH(3)OH)], the Cu(II) atom is coordinated by three N atoms from an anionic 2,6-bis-(1H-benzimidazol-2-yl)pyridine (bbp) ligand, an O atom from a methanol mol-ecule and one N atom from a dicyanamide anion. The crystal structure is stabilized by O-H⋯N and N-H⋯N hydrogen bonds, forming a three-dimensional network.
在标题化合物[Cu(C₁₉H₁₂N₅)(C₂N₃)(CH₃OH)]中，Cu(II)原子由来自阴离子型2,6-双(1H-苯并咪唑-2-基)吡啶(bbp)配体的三个N原子、来自甲醇分子的一个O原子以及来自双氰胺根阴离子的一个N原子配位。晶体结构通过O—H⋯N和N—H⋯N氢键得以稳定，形成三维网络。
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